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Continuous vibronic symmetries in Jahn–Teller models
2018
Journal of Physics: Condensed Matter
We develop a systematic study of Jahn-Teller (JT) models with continuous symmetries by explor- ing their algebraic properties. The compact symmetric spaces corresponding to JT models carrying a Lie group symmetry are identified, and their invariants used to reduce their adiabatic potential energy surfaces into orbit spaces. Each orbit consists of a set of JT distorted molecular structures with equal adiabatic electronic spectrum. Molecular motion may be decomposed into pseudorota- tional and
doi:10.1088/1361-648x/aac89e
pmid:29845973
fatcat:6sspjd2osrdbrcz4e6fw46c2yy