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Conventional and Unconventional Intramolecular Hydrogen Bonding in some Beta-diketones
Org. Chem. Res
This study presents our view of unconventional and conventional intramolecular hydrogen bonds (HBs) for some beta-diketones theoretically and experimentally. According to our results, the groups such as phenyl and t-but in beta positions increase and CF 3 group decrease IHB strength, respectively. For better understanding of the substitution effects, the compounds with similar and different substitutions compared to each other experimentally and theoretically. Comparison between theoretical andfatcat:65xkmgoc3rcldc3c27ctvzgzei