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X-ray studies performed during the growth of CdCO 3 and MnCO 3 crystals from supersaturated aqueous solutions, at fatty acid monolayer templates, reveal that the nucleates are nearly three-dimensional powders below a threshold supersaturation. However, at higher supersaturations, the crystals are preferentially oriented with the ͕0 1 2͖ direction vertical. Scanning electron microscope images of samples transferred to substrates show discrete crystals at low concentrations, while at higherdoi:10.1063/1.2424937 pmid:17176160 fatcat:rddepkxavjeuzmqd2masy73xre