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Lewis base mediated efficient synthesis and solvation-like host–guest chemistry of covalent organic framework-1
2013
Chemical Communications
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N-Lewis base mediated room temperature synthesis of covalent organic frameworks (COFs) starting from a solution of building blocks instead of partially soluble building blocks was developed. This protocol shifts COF synthetic chemistry from sealed tubes to open beakers. Non-conventional inclusion compounds of COF-1 were obtained by vapor phase infiltration of ferrocene and azobenzene, and solvation like effects were established.
doi:10.1039/c2cc37183a
pmid:23208512
fatcat:tnfbydn3jvhetn3snt6wd4rxqm