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A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and information on the mechanism of polymerization are provided. C H E M . C O M M U N . , 2 0 0 3 , 2 2 7 2 -2 2 7 3doi:10.1039/b306701g pmid:14518870 fatcat:wfwpabebabg5jbxcbwwjqpmpaa