The Role of Photocatalysts in Radical Chains of Homolytic Aromatic Substitutions, Radical Addition to Olefins, and Nucleophilic Radical Substitution Mechanisms

Damian E. Yerien, Sebastian Barata-Vallejo, Erwin Mora Flores, Al Postigo
2020 Catalysis science & technology  
Photoinitiated perfluorobutylation reactions of 2-anisidine 1, propenyloxybenzene 2, and 2-mercaptoethanol 3 have been carried out employing commercially available n-C4F9-I as source of C4F9 radicals under three different photocatalysts (PCs) absorbing...
doi:10.1039/d0cy00921k fatcat:vymaio2xazf33pvrzai2ghgpku