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Metal phenylacetate Sesquihydrazinate hydrates of the formula M(PhAc)2.1.5N2H4.H2O where M=Co,Ni or Cd and Metal phenoxyacetate Sesquihydrazinate hydrates M(PhOAc)2.1.5N2H4.H2O Where M=Co, Ni , Cd or Mn have been prepared and characterized by analytical, IR spectral and thermal studies. The composition of complexes have been determined by analytical studies. Infrared spectral data indicate that the bidentate bridging by hydrazine molecules and monodentate coordination by carboxylate ions to thedoi:10.26524/krj59 fatcat:qcy7inrhubdf7ksyag5h5udoom