Stabile Radikalanionen von Aromaten: Strahlenchemische Erzeugung in Gegenwart von Natrium-dihydridobis( 2-methoxyethoxy) aluminat

Nikola Getoff, Matthias W. Haenel, Knut Hildenbrand, Udo-Burckhard Richter, Sonja Solar
1990 Zeitschrift fur Naturforschung A-A Journal of Physical Sciences  
AbstractArenes are reduced at room temperature to their very long-lived radical anions by exposing the solution of the arene and NaAlHThereby 1 is acting as a scavenger for the solvent counter ions which are produced concomitantly to solvated electrons by the radiolysis. The method is very convenient for the ESR and UV-VIS spectroscopy of aromatic radical anions.
doi:10.1515/zna-1990-0211 fatcat:ur5tw5vw5va5fd2dkrrrqdsane