Despite the intense investigation on the NH3-SCR-NOx reaction mechanism catalysed by small pore Cu-CHA zeolites, neither the rate determining step of the process nor the exact nature of the active sites under reaction conditions are clearly established. In this work in situ EPR and IR techniques combined with DFT calculations are applied to the study of the oxidation half-cycle of the NH3-SCR-NOx reaction on Cu-SSZ-13 and Cu-SAPO-34 catalysts. EPR and IR spectroscopies unambiguously show that

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... + is oxidized to Cu 2+ at room temperature in the presence of the reaction mixture (NO, O2 and NH3) or NO and O2, producing adsorbed NO2, nitrites and nitrates. Several pathways are proposed from DFT calculations to oxidize Cu + cations placed in the plane of the 6R ring units of SSZ-13 and SAPO-34 to Cu 2+ , either by NO2 alone or by a mixture of NO and O2, with activation energy barriers lower than 70 kJ mol -1 . The results reported here demonstrate that a reaction mechanism invoking the formation of nitrate/nitrite intermediates on copper cations attached to the zeolite framework can be operational in the low temperature region (T < 350 ºC). Moreover, different intermediates, nitrites vs nitrates, are preferentially stabilized depending on the catalyst composition, silicoaluminophosphate vs aluminosilicate.