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Zur Kristallchemie ungeladener Phosphazen-Basen, I [1] Strukturen zweier Hydrate und eines Acetats von Tris(dimethylamino)methyliminophosphoran / Crystal Chemistry of Uncharged Phosphazene Bases, I [1] Structures of Two Hydrates and an Acetate of Tris(dimethylamino) methyliminophosphorane
1996
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Two hydrates and an acetate of the uncharged, very strong phosphazene base tris(dimethylamino)methyliminophosphorane, (Me2N)3P=NMe (for short Me-P1), have been characterized by their crystal structures. A monohydrate, Me-P1 · H2O , mp. 3°C, is monoclinic with space group P21/n and Z = 4 formula units per unit cell of dimensions a = 8.585, b = 11.107, c = 13.083 Å, and β = 97.76° at -30°C. Another hydrate, Me-P1 · 1.75 H2O, mp. - 11°C. is triclinic with P1̅, Z = 4, a = 7.924, b = 11.768, c =
doi:10.1515/znb-1996-1001
fatcat:kyh5asoacncavhjupl24wgmffq