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Anomalies in the self-diffusion coefficient near the critical point
2002
Journal of Chemical Physics
In this paper we calculate the contribution D s to the self-diffusion coefficient D 0 from the coupling of solute motion to solvent density fluctuations in an infinitely dilute near-critical binary mixture using the methods of fully renormalized kinetic theory in the disconnected approximation. The expression for D s is found to be similar to mode-coupling expressions for diffusion coefficients in dense or supercooled liquids. As a function of the solvent density , and along the critical
doi:10.1063/1.1471549
fatcat:aph5ut5o6bd6xjqmolkd4nyv44