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Grignard-mediated reduction of 2,2,2-trichloro-1-arylethanones
2015
Organic and biomolecular chemistry
2,2,2-Trichloro-1-aryl-ethanones can be reduced by RMgX to the corresponding 2,2-dichloro-1-arylethen-1-olates and trapped with a range of electrophiles. In addition we demonstrate that 2,2-dichloro-1-arylethen-1-olates undergo counter-ion controlled Darzens condensations.
doi:10.1039/c5ob00541h
pmid:25906144
fatcat:c25hnhmc6nfrtfua3gffae5uwe