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Hollow multilayered polyelectrolyte (PE) fibers were fabricated by the combination of the electrostatic layer-by-layer (LBL) and electrospinning methods. The influence of the deposition conditions on the structure of the obtained hollow multilayered PE fibers was studied systemically. The results showed that the formation of multilayered PE films on polystyrene (PS) fiber surface was strongly influenced by the number of repetitions of deposition and the pH value. The spaces among the adjacentdoi:10.1143/jjap.46.6790 fatcat:c2x2ngnnlvc4fikw3m6xfuyrlu