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This paper presents new refined results from the theoretical treatment of electron collision with the Fe-peak element Co3+. We have investigated the relevance of relativistic effects on the accurate representation of the target electron wave functions within theBreit-Pauli R-matrix approach. The calculated values for fine-structure levels are compared with the available experimental data in Atomic Structure Database of the National Institute for Standards and Technology. The agreement betweendoi:10.1155/2013/820635 fatcat:k4czlnoutre37p7pwqmoset4jq