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Li0.93[Li0.21Co0.28Mn0.51]O2 nanoparticles for lithium battery cathode material made by cationic exchange from K-birnessite
Li 0.93 [Li 0.21 Co 0.28 Mn 0.51 ]O 2 nanoparticles with an R-3m space group is hydrothermally prepared from Co 0.35 Mn 0.65 O 2 obtained from an ion-exchange reaction with K-birnessite K 0.32 MnO 2 at 200°C. Even at a hydrothermal reaction temperature of 150°C, the spinel (Fd3m) phase is dominant, and a layered phase became dominant by combining an increase in the temperature to 200°C with an increase in lithium concentration. The as-prepared cathode particle has plate-like hexagonaldoi:10.1016/j.elecom.2006.12.020 fatcat:wubt6hdhy5dw3pxxzpmcwmjbh4