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The relevance of organometallic complexes in the chemistry of the interstellar medium (ISM) was first suggested in the early 90s. This initial proposal has recently been re-considered in the light of new astronomical data, benefiting from pioneering experimental techniques and theoretical methods. In this article, a review of recent theoretical and experimental results obtained for PAHs coordinated to Fe atoms is presented, focusing on: -(i)-the IR spectra of [FePAH] + and [Fe(PAH)2] +doi:10.1051/eas/1146045 fatcat:tn2yj4obcvepphb5dnvniew2ly