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Rotational spectroscopy of methyl benzoylformate and methyl mandelate: structure and internal dynamics of a model reactant and product of enantioselective reduction
2015
Physical Chemistry, Chemical Physics - PCCP
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Rotational spectra of a prochiral ester, methyl benzoylformate, and the product of its enantioselective reduction, (R)-(–)-methyl mandelate, were measured, and minimum energy conformers and methyl rotation barriers were determined.
doi:10.1039/c5cp03114a
pmid:26234934
fatcat:7v4pbjaos5guje7wajprbzllzy