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Structure and Electrochemistry of Carbon-Metal Fluoride Nanocomposites Fabricated by Solid-State Redox Conversion Reaction
2005
Journal of the Electrochemical Society
Utilizing a solid-state redox-driven conversion reaction enabled by mechanochemistry, conductive C:FeF 3 nanocomposites were fabricated from insulative CF 1 :FeF 2 precursors. All reactions were characterized by X-ray diffraction and Fourier transform infrared spectroscopy. The latter provided insights to the progression of the CF and C phases and the metal fluoride during the course of the reaction. Such nanocomposites resulted in a four order of magnitude increase in electrical conductivity
doi:10.1149/1.1842035
fatcat:4jwnd5oj3rbobbln5indg4ol5e