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Nucleation mediated interfacial precipitation for architectural perovskite films with enhanced photovoltaic performance
2017
Nanoscale
S2 Kinetics curves drawn by classical nucleation theory calculation. Homogeneous nucleation 1 . In classical nucleation theory, supersaturated solution in which the concentration of solute (c) exceeding the equilibrium solubility ( ) possesses a high Gibbs free * energy, when the supersaturation ( ) achieves a critical point 1-4 , nucleation will take △ = - * place to reduce the energy and keep the system to be stable. The reduction of Gibbs free energy
doi:10.1039/c6nr08741h
pmid:28150836
fatcat:jbmghrgrzjhlxg2i5zfzmqnmny