Coherent Subnanometric Plate Precipitates Formed during Crystallization of As-Sputtered Ti-Ni films

K. Ogawa, T. Kikuchi, S. Kajiwara, T. Matsunaga, S. Miyazaki
1997 Journal de Physique IV : Proceedings  
It is shown by high resolution electron microscopy that coherent plate precipitates with 0.5-1 nrn thickness are formed in Ti-rich Ti-Ni thin films when heat treated directly eom the sputter-deposited amorphous state near the crystallization temperature. The precipitates are Ti-rich and formed on (100) planes of the B2 matrix phase with perfect coherency. The crystal structure of the precipitate is a body centered tetragonal with the oaxis normal to the habit plane. Owing to the existence of
more » ... se coherent subnanometric precipitates, the parent phase is greatly strengthened, resulting in very excellent shape memory properties such as 6 % recoverable shape memory strain at the stress level of 300 MPa without any appreciable plastic deformation.
doi:10.1051/jp4:1997534 fatcat:nujw2j3f2rhx3lm42tdarkoqgy