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Chiral phosphonite ligands (S,R b )-5a, (S,S b )-5b, (R,R b )-6a and (R,S b )-6b are introduced, comprising a MOP-type backbone with a binol-based binaphthyl group bound to the phosphorus. Their reaction with [Pd(η 3 -C 4 H 7 )Cl] 2 affords η 3 -methallylpalladium chloride complexes 7a/b and 8a/b which have been isolated and structurally characterised. Solid-state and solution studies indicate subtle differences in their coordination behaviour, which ultimately affects their efficacy in thedoi:10.1039/c2dt12214f pmid:22307224 fatcat:gpqbddu3ojfn3iixljxbs6fbs4