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Three small forested catchments in the Czech Republic, each underlain by chemically contrasting silicate rocks, were investigated with focus on long-term atmospheric deposition of S, and pools and fluxes of Ca and Mg. Pools of Ca and Mg reflected geological substrate (granite: Ca, Mg poor, amphibolite: Ca, Mg rich, serpentinite: Ca poor, Mg rich). Long-term fluxes of S, Ca and Mg were tightly connected.doi:10.1051/e3sconf/20199806007 fatcat:tmnqrk2jdjew3ne37k3gbm4mli