We investigate the effect of cantori on momentum diffusion in a quantum system. Ultracold caesium atoms are subjected to a specifically designed periodically pulsed standing wave. A cantorus separates two chaotic regions of the classical phase space. Diffusion through the cantorus is classically predicted. Quantum diffusion is only significant when the classical phase-space area escaping through the cantorus per period greatly exceeds Planck's constant. Experimental data and a quantum analysis confirm that the cantori act as barriers.