We examine three approaches to the problem of source classification in catalogues. Our goal is to determine the confidence with which the elements in these catalogues can be distinguished in populations on the basis of their spectral energy distribution (SED). Our analysis is based on the projection of the measurements onto a comprehensive SED model of the main signals in the considered range of frequencies. We first first consider likelihood analysis, which half way between supervised and

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... ervised methods. Next, we investigate an unsupervised clustering technique. Finally, we consider a supervised classifier based on Artificial Neural Networks. We illustrate the approach and results using catalogues from various surveys. i.e., X-Rays (MCXC), optical (SDSS) and millimetric (Planck Sunyaev-Zeldovich (SZ)). We show that the results from the statistical classifications of the three methods are in very good agreement with each others, although the supervised neural network-based classification shows better performances allowing the best separation into populations of reliable and unreliable sources in catalogues. The latest method was applied to the SZ sources detected by the Planck satellite. It led to a classification assessing and thereby agreeing with the reliability assessment published in the Planck SZ catalogue. Our method could easily be applied to catalogues from future large survey such as SRG/eROSITA and Euclid.