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Self-assembly of end-tethered nanorods in a neat system and role of block fractions and aspect ratio
2010
Soft Matter
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We report a computational study of the self-assembly of end-tethered nanorods in a neat system (no solvent). We present morphological phase diagrams for low and moderate aspect ratio rods as a function of inverse temperature vs. relative tether fraction. Our simulations predict that the end-tethered rods self-assemble into hexagonally arranged chiral cylinders, hexagonally perforated lamellae, monolayer and bilayer arrowhead structures and wavy lamellae. For high aspect ratio tethered nanorods
doi:10.1039/b917403f
fatcat:pcisyhg2rbft3bxtb6hsm3y7zu