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Absrracr Lipophilic metal complexes, displaying one electron redox activity, are used as carriers for the transport of electrons across bulk liquid membranes from an aqueous reducing phase to an aqueous oxidizing phase. The [FeIII,lI(bpy)313+/2+ redox system (bpy = 4,4'-di-rerr-butyl-2,2'dipyridyl, 1) transports electrons from both cationic and anionic aqueous reducing agents to aqueous Ce(1V) and counter-transports perchlorate ions in the opposite direction. Electron/chloride ion crossdoi:10.1351/pac199062061119 fatcat:ni2fw6bo2jcdxckasj7t2y45r4