L.—The condensation of oxalic acid and resorcinol

John Theodore Hewitt, Arthur Ernest Pitt
1899 Journal of the Chemical Society Transactions  
THE condensation of osalic acid and resorcinol has been studied by various chemists, interaction being induced either at high temperatures or by the use of a condensing agent, Apparently, the first to study the reaction was A. von Baeyer (Bey., 1871,4,662), who stated that, on heating with sulphuric acid, a yellow substance was obtained which does not exhibit fluorescence in solution, and is apparently similar to euxanthone, with the exception that i t cannot be sublimed. Von Baeyer,
more » ... s, thought i t probable that the substance was a mixture in which euxanthone was present, The next work on tEie subject was that of Claw and Andreae (Ber., 1877, 10, 1305), who heated a mixture of resorcinol (1 mol.) with dehydrated oxalic acid (2 mols.) in sealed tubes for 2 to 3 hours at 2 0 0 O ; the product mas mixed with alcohol and poured into water, a substance being thrown down which was purified by soliltion in alcohol and reprecipitation by water. When dissolved in alkalis, i t shows a moss-green fluorescence, which is always exhibited, no matter how many times the substance has been taken up by alcohol. The
doi:10.1039/ct8997500518 fatcat:hfwyxlj6gngujb5zhkpcqhgtji