Cross-Coupling Reactions of Organosilicon Compounds: New Concepts and Recent Advances

Scott Eric Denmark, Ramzi Farah Sweis
2002 Chemical and pharmaceutical bulletin  
This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di-and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groups into organic molecules and the range of organic electrophiles that can be used are emphasized.
doi:10.1248/cpb.50.1531 pmid:12499586 fatcat:lvwvso7k3vf3vjx33vzb424psi