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MESO AND RACEMIC 1,1-BIS (BENZYLSULFINYL)-2-ETHYLBUTANE. A b-DISULFOXIDE PRO-LIGAND WITH STERIC RESTRICTIONS
2016
Journal of the Chilean Chemical Society (Print)
Coordination chemistry of disulfoxides is of interest in inorganic chemistry given the well-known metal coordination through oxygen or sulfur atoms. 1 Ethylene and propylene bridged disulfoxide pro-ligands, coordinate to metals, forming coordinated and chelated complexes, demonstrating its flexibility in the formation of such complexes. 2 Some of these compounds have demonstrated interesting properties in medicinal chemistry 3 and asymmetric catalysis 4 and their synthesis is of importance for
doi:10.4067/s0717-97072016000400001
fatcat:fdo6phy3jfc7bfjiy2k45myzya