Electrochemical Polarization

M. Stern, A. L. Geaby
1957 Journal of the Electrochemical Society  
At low overvoltage values, deviations from Tafel behavior for a noncorroding electrode are due primarily to the reverse reaction of the oxidation-reduction system, and at high overvoltages to concentration and/or resistance polarization. It is shown further that the practice of placing straight lines through a few experimental points is extremely hazardous, while the indiscriminate introduction of "breaks" is contrary to the electrode kinetics described. ) unless CC License in place (see
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doi:10.1149/1.2428496 fatcat:7pdipcjdcfhwlomfxu743zpp24