A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2020; you can also visit the original URL.
The file type is
We report a simple and novel molecular design strategy to enhance rISC in boron-based donor-acceptor systems to achieve improved delayed fluorescence characteristics. Dianthrylboryl ((An)2B)-based aryl aminoboranes 1 (donor: phenothiazine) and 2 (donor: N,N-diphenylamine) were synthesized by a simple one-pot procedure. The energy of the electronic excited states in 1 and 2 were modulated by varying the arylamine donor strength and electronic coupling between D and A moieties. The presence of adoi:10.3389/fchem.2020.541331 pmid:33195044 pmcid:PMC7581868 fatcat:hup23esbjreuro7l55f65eiejm