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Heuristic Considerations Suggesting a Role for Electron Pairing in Thermodynamically Consistent Pathways of Enzyme Catalysis
1978
Zeitschrift fur Naturforschung A-A Journal of Physical Sciences
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AbstractNuclear motions accompanying enzyme catalysis are described in terms of a hypothetical reaction mechanism in which instabilities of electronic structure arise from short-lived pairing resonances of parallel spin electrons. A pairing interaction is proposed which has its basis in confinement constraints imposed by complex formation.
doi:10.1515/zna-1978-1014
fatcat:rkqdr26mvbazbbfx4xpampwunm