Various Behaviors of Carbon Atoms. New Metastable Forms Suggesting Modification of sp-hybridization
多様な炭素の挙動 準安定相と混成軌道概念拡大の可能性

Hisako HIRAI, Ken-ichi KONDO
1992 Journal of the Mineralogical Society of Japan  
Carbon exhibits a wide variety of behaviors that depend on the surrounding environment and processing techniques, reflecting different kinds of chemical bond nature. Carbon forms have been calssified by the type of sp hybridization, sp1, sp2 and sp3. Recently, several metastable forms were synthesized experimentally and also a few hypothetical forms were proposed on the base of theoretical calculation. These carbon forms represent some modified sp2 and/or spa bonds. This suggests that
more » ... ion of carbon atom is allowed to extend from those defined by an discrete integer and geometric symmetry to those by fraction and asymmetry.
doi:10.2465/gkk1952.21.269 fatcat:pjq2tlyybvecjeqv7khhnbtfxi