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Analyzing Mechanisms in Co(I) Redox Catalysis Using a Pattern Recognition Platform
[post]
2020
unpublished
Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential, which strongly inhibit the efficient activation of substrates in electrolysis. Despite the benefits brought by redox catalysis, establishing the precise nature of substrate activation remains challenging. Herein, we determine that a Co(I) complex bearing two
doi:10.26434/chemrxiv.13017161
fatcat:k7tjvx7tcrenfb7t6oyk2aghqq