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Novel boratabenzene-phosphole complexes have been prepared and structurally characterized. The electronic communication between the two heterocyclic rings linked by a P-B bond and the aromaticity of these systems were probed using crystallographic and density functional studies. 5doi:10.1039/c0cc01999b pmid:20714565 fatcat:qlsrgwwidjhurc47n6do6c27cq