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Isotropic-nematic phase transition in athermal solutions of rod-coil diblock copolymers
2007
Journal of Chemical Physics
We present a hybrid method to investigate the isotropic-nematic ͑I-N͒ transition in athermal solutions of rod-coil copolymers. This method incorporates the scaled-particle theory for semiflexible chains with two-chain Monte Carlo simulation for the osmotic second virial coefficient and for the angle-dependent excluded volume. We compare the theoretical prediction with Monte Carlo simulations for fused rod-coil copolymers and find good agreement for both the equation of state and the
doi:10.1063/1.2751497
pmid:17655458
fatcat:uc4kqubwxra4tf72cjoskw64ua