Synthesis of tetrahydrobenzo[b]pyran under catalysis of NH 4 Al(SO 4 ) 2 ·12H 2 O (Alum)

Ali A. Mohammadi, Mohammad R. Asghariganjeh, Armin Hadadzahmatkesh
2017 Arabian Journal of Chemistry  
A simple and efficient one-pot synthesis of tetrahydrobenzo[b]pyrans from the threecomponent reaction between dimedone, aldehydes, and active methylene compounds using NH 4 Al(SO 4 ) 2 AE12H 2 O (Alum) as a catalyst at 80 °C is described. The catalyst exhibits remarkable reactivity and is reusable. ª 2013 Production and hosting by Elsevier B.V. on behalf of King Saud University.
doi:10.1016/j.arabjc.2013.07.055 fatcat:z62aqwarvnej7dp42bbi2w2o5u