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A highly reduced cyanogen ligand derived from cyanide reductive coupling
2012
Chemical Communications
The synthesis, structure, and spectroscopic features of a bimetallic cyanogen complex obtained from the reductive coupling of cyanide by a niobium(IV) precursor are described, and a mechanism for the coupling reaction is proposed based on DFT calculations. Scheme 1
doi:10.1039/c2cc17212g
pmid:22343665
fatcat:3ttr4ldlbra3dcpybpnfv5ucna