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The deposition of calcium fluoride nanoparticles on single crystal chips of calcium fluoride was studied. CaF2 nanoparticles were synthesized by co-precipitation from aqueous nitrate solutions using hydrofluoric acid as a fluorinating agent at a batch system. The prepared samples were examined by atomic force microscopy, scanning electron microscopy, transmission electron microscopy and optical transmission. There is an inhomogeneous coating of the substrate surface with submicron particles ofdoi:10.17308/kcmf.2021.23/3681 fatcat:ad6olaozfngszh6ehg5k2cgnxy