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Darstellung und Charakterisierung von Dekachlorodiiridat(IV), [Ir2Cl10]2-, und Normalkoordinatenanalyse an Dioktaederkomplexen des Typs [M2X10]2-, M = Re, Os, Ir, Pt; X = Cl, Br / Preparation and Characterization of Decachlorodiiridate(IV), [Ir2Cl10]2-, and Normal Coordinate Analysis of Bioctahedral Complexes [M2X10]2-, M = Re, Os, Ir, Pt; X = Cl, Br
1992
Zeitschrift für Naturforschung. B, A journal of chemical sciences
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On heating the tetraethylammonium salt of [IrCl6]2- with trifluoroacetic acid the edge sharing bioctahedral anion [Ir2Cl10]2- is formed, the IR and Raman spectra of which are assigned according to point group D2h. Normal coordinate analyses, based on a general valence force field, for [M2X10]2-, M = Re, Os, Ir, Pt; X = Cl, Br have been performed, resulting in a good agreement of the calculated frequencies with the bands observed in the IR and Raman spectra. Due to the stronger bonding of the
doi:10.1515/znb-1992-0810
fatcat:kzfbnxckpvg3dhprz2ujgdrmfi