Ruthenium Vinylidene Complexes

Valerian Dragutan, Ileana Dragutan
2004 Platinum Metals Review  
Previous papers recently published in this Journal have highlighted the role and scope of platinum group metals in the development of metathesis catalysts (1, 2). Following the seminal discovery of the highly active and stereoselective tungsten and molybdenum imido alkylidene metathesis catalysts, for example, 1 and 2 (R = alkyl groups) by Schrock and coworkers (3, 4), an important class of ruthenium bisphosphane alkylidene catalysts, for example, 3 and 4, have been disclosed and successfully
more » ... plied in metathesis reactions by Grubbs and coworkers (5, 6). R = phenyl (Ph), isopropyl (iPr) or cyclohexyl (Cy) R' = phenyl (Ph) or tert-butyl (tBu) groups Mes = mesityl R = phenyl (Ph), isopropyl (iPr) or cyclohexyl (Cy) R' = phenyl (Ph) or tert-butyl (tBu) groups
doi:10.1595/147106704x4835 fatcat:cdk45xxigjcxhcqsioxeqxhfzm