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Metallophilic Interactions in Bimetallic Cyclometalated Platinum(II) N‐Heterocyclic Carbene Complexes
2021
European Journal of Inorganic Chemistry
Platinum(II) complexes with rigid and electron donating ligands are efficient phosphorescent emitters at room temperature. However, the excited-state lifetimes of these complexes are, in general, relatively long. This problem, which can result in the degradation of the emitter, can be overcome by exploiting the natural tendency of platinum to form metallophilic interactions and aggregates. Herein, we report platinum(II) bimetallic complexes with 100 % quantum yield and at the same time
doi:10.1002/ejic.202100456
fatcat:ug232l76rzdlzgkdpnuz7sofv4