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Investigations toward a Non-Aqueous Hybrid Redox-Flow Battery with a Manganese-Based Anolyte and Catholyte
A new all-Manganese flow battery (all-MFB) as a non-aqueous hybrid redox-flow battery is reported. The discharged active material [Cat]2[MnIICl4] (Cat = organic cation) utilized in both half-cells supports a long cycle life. The reversible oxidation of [MnIICl4]2− to [MnIIICl5]2− at the positive electrode and manganese metal deposition from [MnIICl4]2− at the negative electrode give a cell voltage of 2.59 V. Suitable electrolytes are prepared and optimized, followed by a characterization indoi:10.17169/refubium-31143 fatcat:o6gumnd43zfdzmqvf3qpzbmt6a