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アシル化糖の位置選択的合成とその転位 糖類水酸基の位置選択的修飾
Regioselective Syntheses of Acylated Mono-saccharides and Their Acyl Migration
1984
Journal of Synthetic Organic Chemistry, Japan
Regioselective Syntheses of Acylated Mono-saccharides and Their Acyl Migration
Mono-saccharides and Their Acyl Migration. Regioselective Modifications of a Hydroxyl Group in Carbohydrates Yoshisuke TSUDA* and Kimihiro YOSHIMOTO* This article critically reviews the reactivity of hydroxyl groups in mono-saccharides toward direct acylation and describes the method of regioselective modifications (acylation, alkylation, etc) of a hydroxyl group without blocking-deblocking technique via cyclic tin intermediates. O-Acyl migration in mono-O-acyl derivatives of D-glucose and L-arabinose under various conditions is also discussed.
doi:10.5059/yukigoseikyokaishi.42.479
fatcat:qftgtxg6rvgmhn36ehp7l3oum4