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Two D–A type polymers based on the gTDPP as the acceptor and gTVT and gTBTT as the donor have been developed. The donor unit affects the backbone curvature and the aggregation properties of the mixed conductors, regulating their performance in OECTs.doi:10.1039/d1tc02994k fatcat:et5ebw4jandyrlq4pmybhvjdni