DISCUSSION. ON THE APPLICATION OF ZINC BY THE PROCESS OF ELECTRO-DEPOSITION, FOR THE PRESERVATION OF IRON, AS APPLIED TO ENGINEERING AND OTHER PURPOSES

F PELLATT, J WALKER
1843 Minutes of the Proceedings of the Institution of Civil Engineers  
with zinc and copper by the process of electro-deposition, which he described. The pieces of iron were first rendered perfectly clean and free from oxyde by plunging them into a bath of heated sulphuric acid and water : they were then placed in a cold solution of sulphate of zinc. The positive pole of a galvanic battery being attached to a zinc plate, and the negative pole to the piece intended to be covered with metal, the deposition commenced equally all over it, and was continued as long as
more » ... as considered necessary. By this process the pure metal alone could be deposited, and the amalgamation of the zinc and iron, which occurred when the iron plates were dipped into melted metal, was avoided. For zincing, he preferred an acid to an alkaline solution of the metallic salts. Some thin plates, which had heen exposed for eight months, on roofs in London, did not exhibit any appearance of rust. The process could be applied on any scale, as all the apparatus that was necessary was some wooden troughs to contain the solution and the pieces of metal to be covered. H e had not made accurate experiments as to the e6cacy of the process, when applied to iron exposed to the action of sea-water, but he feared the result, on account of the formation of muriate of zinc.
doi:10.1680/imotp.1843.24668 fatcat:jxvmkgagy5avtfaka5zjhdvviu