Characterization of Solid Residues Obtained from Supercritical Ethanol Liquefaction of Swine Manure

Rui Li, Bo Zhang, Shuangning Xiu, Hui Wang, Lijun Wang, Abolghasem Shahbazi
2015 American Journal of Engineering and Applied Sciences  
Animal wastes are considered as renewable energy resources, which contain a great energy potential. For this study, swine manure was treated with supercritical ethanol within the reaction temperature range of 240-360°C to produce bio-oil, resulting in a significant amount of solid residues. Solid residues were characterized by using Fourier Transform Infrared (FT-IR), Scanning Electron Microscopic (SEM), surface area, elemental and thermogravimetric (TG) analyses. Solid residues were mainly
more » ... osed of carbon (26-29 wt%) and ash (35-45 wt%) and exhibited low surface areas (11-17 m 2 /g). The analyses indicated an incomplete conversion of lignocellulosic components and thermal chemical reactions including hydrolysis, dehydration, decarboxylation, aromatization and condensation. Supercritical ethanol liquefaction is considered as a feasible way to remove oxygen and utilize carbon and hydrogen in swine manure to produce carbonaceous materials and energy condensed bio-fuels.
doi:10.3844/ajeassp.2015.465.470 fatcat:sooucuhlnnfstessgbifmejfie