Synthesis, Characterization and Thermal Analysis of an Organic-Inorganic Hybrid Salt Involving Trans-Diaquabis(oxalato-κ2O1,O2)chromate(III) Complex Anion with Piperidinium as Counter Cation

Pierre R. Ndong, Martin Signé, Patrice T. Kenfack, Yves A. Mbiangué, Gouet Bebga, Emmanuel Wenger
2020 Crystal Structure Theory and Applications  
A new organic-inorganic hybrid salt pipéridinium trans-diaquabis(oxalato)chromate(III) tetrahydrate, (C 5 H 10 NH 2 )[Cr(C 2 O 4 ) 2 (H 2 O) 2 ]·4H 2 O (1), has been synthesized in water and characterized by FTIR and UV-Vis spectroscopies, elemental and thermal analyses and by single-crystal X-ray diffraction. 1 crystallizes in the orthorhombic non-centrosymmetric space group Cmc2 1 with the unit cell parameters a = 7.4329(3), b = 9.9356(5), c = 23.6756(11) Å, α = β = γ = 90˚, V = 1748.45(14) Å
more » ... , V = 1748.45(14) Å 3 and Z = 4. The structure of 1 consists of
doi:10.4236/csta.2020.92004 fatcat:2fbhj2piufebfduoigdpmafodm