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General procedure: all operations were performed with rigorous exclusion of air and water; standard Schlenk, high-vacuum and glovebox techniques were used for the preparation or handling of organometallic compounds and alumina supported materials. The silica supported tantalum hydride 1a and the alumina supported tungsten hydride 1b were prepared as already reported. i Elemental analyses were performed at the Service Central d'Analyses of CNRS in Solaize (France). Reaction of isobutane anddoi:10.1039/b823226a pmid:19532877 fatcat:ddgrlrurpff6fnxjuzvrzayaum