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In this study, the steam oxidation behavior of Cr-coated Zry-4 alloy at 1000 • C and the various interesting phenomena observed during the oxidation process were investigated. During oxidation, Sn in the Zry-4 substrate diffused into the coating and precipitated in the Cr 2 O 3 scale. The Kirkendall effect of these Sn-containing precipitates then generated microcavities. Furthermore, the outward diffusion behavior of Zr and the selective oxidation mechanism of the Zr particles were studied.doi:10.5445/ir/1000135986 fatcat:jel523uhjbay7iek4gixgp7fs4